Exfoliation of Threading Dislocation‐Free, Single‐Crystalline, Ultrathin Gallium Nitride Nanomembranes. (19th December 2013)

• Record Type: Journal Article
• Authors: ElAfandy, Rami T.; Majid, Mohammed A.; Ng, Tien Khee; Zhao, Lan; Cha, Dongkyu; Ooi, Boon S.
• Is Part Of: Advanced functional materials. Volume 24:Number 16(2014)
• Page Start: 2305
• Page End: 2311
• Publication Date: 2013-12-19
• Subjects: Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201303001
• Languages: English
• ISSNs: 1616-301X

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>Despite the recent progress in gallium nitride (GaN) growth technology, the excessively high threading dislocation (TD) density within the GaN crystal, caused by the reliance on heterogeneous substrates, impedes the development of high‐efficiency, low‐cost, GaN‐based heterostructure devices. For the first time, the chemical exfoliation of completely TD‐free, single‐crystalline, ultrathin (tens of nanometers) GaN nanomembranes is demonstrated using UV‐assisted electroless chemical etching. These nanomembranes can act as seeding layers for subsequent overgrowth of high‐quality GaN. A model is proposed, based on scanning and transmission electron microscopy as well as optical measurements to explain the physical processes behind the formation of the GaN nanomembranes. These novel nanomembranes, once transferred to other substrates, present a unique and technologically attractive path towards integrating high‐efficiency GaN optical components along with silicon electronics. Interestingly, due to their nanoscale thickness and macroscopic sizes, these nanomembranes may enable the production of flexible GaN‐based optoelectronics.</p> </abstract>