Synthesis of Dibenzophosphole Oxides via Palladium‐Catalyzed Intramolecular Direct Arylation Reactions of ortho‐Halodiarylphosphine Oxides. Issue 6 (20th March 2014)

• Record Type: Journal Article
• Authors: Cui, Yuming; Fu, Lingzi; Cao, Jian; Deng, Yuan; Jiang, Jianxiong
• Is Part Of: Advanced synthesis & catalysis. Volume 356:Issue 6(2014)
• Page Start: 1217
• Page End: 1222
• Publication Date: 2014-03-20
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201301081
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A palladium‐catalyzed intramolecular direct arylation reaction was developed and two efficient one‐pot sequential direct arylation/Suzuki–Miyaura coupling and intra/intermolecular direct arylation reations were also realized. The method provides a simple and straightforward procedure for the synthesis and further functionalization of dibenzophosphole oxides from easily accessible <italic>ortho</italic>‐halodiarylphosphine oxides in good to excellent yields.</p> <p> <boxed-text content-type="graphic" position="anchor" orientation="portrait"> <graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg58f9z43d" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> </boxed-text> </p> </abstract>