Synthesis of a Covalent Monolayer Sheet by Photochemical Anthracene Dimerization at the Air/Water Interface and its Mechanical Characterization by AFM Indentation. (17th December 2013)

• Record Type: Journal Article
• Authors: Payamyar, Payam; Kaja, Khaled; Ruiz‐Vargas, Carlos; Stemmer, Andreas; Murray, Daniel J.; Johnson, Carey J.; King, Benjamin T.; Schiffmann, Florian; VandeVondele, Joost; Renn, Alois; Götzinger, Stephan; Ceroni, Paola; Schütz, Andri; Lee, Lay‐Theng; Zheng, Zhikun; Sakamoto, Junji; Schlüter, A. Dieter
• Is Part Of: Advanced materials. Volume 26:Number 13(2014)
• Page Start: 2052
• Page End: 2058
• Publication Date: 2013-12-17
• Subjects: Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201304705
• Languages: English
• ISSNs: 0935-9648

Abstract

<abstract abstract-type="graphical" xml:lang="en" id="adma201304705-abs-0001"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Covalent monolayer sheets in 2 hours</bold>: spreading of threefold anthracene‐equipped shape‐persistent and amphiphilic monomers at the air/water interface followed by a short photochemical treatment provides access to infinitely sized, strictly monolayered, covalent sheets with in‐plane elastic modulus in the range of 19 N/m. <boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg52wtn407" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>