Construction of Mesoporous Frameworks with Vanadoborate Clusters1. Issue 14 (3rd March 2014)

• Record Type: Journal Article
• Authors: Chen, Hong; Yu, Zheng‐Bao; Bacsik, Zoltán; Zhao, Huishuang; Yao, Qingxia; Sun, Junliang
• Is Part Of: Angewandte Chemie international edition. Volume 53:Issue 14(2014)
• Page Start: 3608
• Page End: 3611
• Publication Date: 2014-03-03
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201311122
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A new porous vanadoborate was synthesized by employing the scale chemistry theory with the vanadoborate cluster V₁₀B₂₈. The twofold interpenetrated <bold>lvt</bold> network was assembled with zinc‐containing elliptical vanadoborate clusters and Zn polyhedra. The single <bold>lvt</bold> framework contains a three‐dimensional 38×38×20 ring channel system with the pore size (24.7×12.7 Å) reaching the mesoscale, thus indicating the possibility of constructing 3D ordered mesopores with vanadoborate clusters. The porosity of the SUT‐7 structure was confirmed by CO₂ adsorption of the as‐synthesized materials.</p> </abstract>