Direct α‐Siladifluoromethylation of Lithium Enolates with Ruppert‐Prakash Reagent via CF Bond Activation. Issue 10 (7th February 2014)
- Record Type:
- Journal Article
- Title:
- Direct α‐Siladifluoromethylation of Lithium Enolates with Ruppert‐Prakash Reagent via CF Bond Activation. Issue 10 (7th February 2014)
- Main Title:
- Direct α‐Siladifluoromethylation of Lithium Enolates with Ruppert‐Prakash Reagent via CF Bond Activation
- Authors:
- Hashimoto, Ryota
Iida, Toshiaki
Aikawa, Kohsuke
Ito, Shigekazu
Mikami, Koichi - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The direct α‐siladifluoromethylation of lithium enolates with the Ruppert–Prakash reagent (CF<sub>3</sub>TMS) is shown to construct the tertiary and quaternary carbon centers. The Ruppert–Prakash reagent, which is versatile for various trifluoromethylation as a trifluoromethyl anion (CF<sub>3</sub><sup>−</sup>) equivalent, can be employed as a siladifluoromethyl cation (TMSCF<sub>2</sub><sup>+</sup>) equivalent by CF bond activation due to the strong interaction between lithium and fluorine atoms.</p> </abstract>
- Is Part Of:
- Chemistry. Volume 20:Issue 10(2014)
- Journal:
- Chemistry
- Issue:
- Volume 20:Issue 10(2014)
- Issue Display:
- Volume 20, Issue 10 (2014)
- Year:
- 2014
- Volume:
- 20
- Issue:
- 10
- Issue Sort Value:
- 2014-0020-0010-0000
- Page Start:
- 2750
- Page End:
- 2754
- Publication Date:
- 2014-02-07
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3765 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/chem.201304473 ↗
- Languages:
- English
- ISSNs:
- 0947-6539
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3168.860500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4248.xml