Alkyne/Alkene/Allene‐Induced Disproportionation of Cationic Gold(I) Catalyst. Issue 11 (12th February 2014)
- Record Type:
- Journal Article
- Title:
- Alkyne/Alkene/Allene‐Induced Disproportionation of Cationic Gold(I) Catalyst. Issue 11 (12th February 2014)
- Main Title:
- Alkyne/Alkene/Allene‐Induced Disproportionation of Cationic Gold(I) Catalyst
- Authors:
- Kumar, Manish
Jasinski, Jacek
Hammond, Gerald B.
Xu, Bo - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The first detailed experimental study of the deactivation of cationic gold was conducted, and the influence of each component in the reaction system (substrate, counterion, solvent) on the decay process was examined. It was found that a substrate (alkyne/allene/alkene)‐induced disproportionation of gold(I) may play a key role in the decay process. Our mechanism is supported by kinetic, XPS, voltammetry studies, and high‐resolution ESI‐MS data.</p> </abstract>
- Is Part Of:
- Chemistry. Volume 20:Issue 11(2014)
- Journal:
- Chemistry
- Issue:
- Volume 20:Issue 11(2014)
- Issue Display:
- Volume 20, Issue 11 (2014)
- Year:
- 2014
- Volume:
- 20
- Issue:
- 11
- Issue Sort Value:
- 2014-0020-0011-0000
- Page Start:
- 3113
- Page End:
- 3119
- Publication Date:
- 2014-02-12
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3765 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/chem.201304271 ↗
- Languages:
- English
- ISSNs:
- 0947-6539
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3168.860500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4139.xml