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A Direct, Modular, and Efficient Construction of the PCP Structural Motif through Coupling of Manganese Carbyne Complexes with Phosphines. Issue 8 (30th January 2014)
Record Type:
Journal Article
Title:
A Direct, Modular, and Efficient Construction of the PCP Structural Motif through Coupling of Manganese Carbyne Complexes with Phosphines. Issue 8 (30th January 2014)
Main Title:
A Direct, Modular, and Efficient Construction of the PCP Structural Motif through Coupling of Manganese Carbyne Complexes with Phosphines
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Easily available carbyne complexes of manganese were used as a source of carbyne fragments in an unconventional synthesis of backbone‐substituted diphosphinomethanes and cyclic P‐ylides upon coupling with secondary or tertiary phosphines, respectively, followed by demetalation under mild conditions.</p> </abstract>