A Copper(I)‐Catalyzed Three‐Component Domino Process: Assembly of Complex 1, 2, 3‐Triazolyl‐5‐Phosphonates from Azides, Alkynes, and H‐Phosphates. Issue 43 (23rd September 2013)

• Record Type: Journal Article
• Authors: Li, Lingjun; Hao, Guoliang; Zhu, Anlian; Fan, Xincui; Zhang, Guisheng; Zhang, Lihe
• Is Part Of: Chemistry. Volume 19:Issue 43(2013)
• Page Start: 14403
• Page End: 14406
• Publication Date: 2013-09-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201303324
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Three is better than one!</bold> A new copper‐catalyzed tricomponent reaction of a terminal alkyne, organic azide, and <italic>H</italic>‐phosphate (CuAA[P]C) leads to a structurally diverse polysubstituted 1, 2, 3‐triazolyl‐5‐phosphonate, which provides an efficient tool for the direct introduction of phosphonic acid groups by a "click reaction" (see scheme).<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t3tq6xm" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>