Ligand–Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation. Issue 50 (7th November 2013)

• Record Type: Journal Article
• Authors: Musa, Sanaa; Filippov, Oleg A.; Belkova, Natalia V.; Shubina, Elena S.; Silantyev, Gleb A.; Ackermann, Lutz; Gelman, Dmitri
• Is Part Of: Chemistry. Volume 19:Issue 50(2013)
• Page Start: 16906
• Page End: 16909
• Publication Date: 2013-11-07
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201303311
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Ligand–metal cooperation</bold>: A new ligand–metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H₂ activation and CH bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the metal center and proceeds without change of the oxidation state of the metal.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t3t0hm5" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>