New FeI–FeI Complex Featuring a Rotated Conformation Related to the [2 Fe]H Subsite of [Fe–Fe] Hydrogenase. Issue 46 (14th October 2013)

• Record Type: Journal Article
• Authors: Munery, Sabrina; Capon, Jean‐François; De Gioia, Luca; Elleouet, Catherine; Greco, Claudio; Pétillon, François Y.; Schollhammer, Philippe; Talarmin, Jean; Zampella, Giuseppe
• Is Part Of: Chemistry. Volume 19:Issue 46(2013)
• Page Start: 15458
• Page End: 15461
• Publication Date: 2013-10-14
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201303316
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Rotated geometry</bold>: The first example of a dinuclear iron(I)–iron(I) complex featuring a fully rotated geometry related to the active site of [Fe–Fe] hydrogenase is reported (see figure).<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t7pxmmm" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>