Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the Hred State?. Issue 46 (15th October 2013)

• Record Type: Journal Article
• Authors: Wang, Wenguang; Rauchfuss, Thomas B.; Moore, Curtis E.; Rheingold, Arnold L.; De Gioia, Luca; Zampella, Giuseppe
• Is Part Of: Chemistry. Volume 19:Issue 46(2013)
• Page Start: 15476
• Page End: 15479
• Publication Date: 2013-10-15
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201303351
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A lucky break</bold>: A combination of steric pressure and electron asymmetry has provided the first example of a diiron dithiolate that is both rotated and basic. The present work establishes the feasibility of a hydride free rotated structure for the H_red state of the enzyme (see figure).<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t7pxp0q" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>