A New Remote Control for Traceless meta‐CH Olefination of Phenols. Issue 12 (9th September 2013)

• Record Type: Journal Article
• Authors: Martínez, Claudio; Muñiz, Kilian
• Is Part Of: ChemCatChem. Volume 5:Issue 12(2013:Dec.)
• Page Start: 3502
• Page End: 3503
• Publication Date: 2013-09-09
• Subjects: Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201300538
• Languages: English
• ISSNs: 1867-3880

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Ghosting the directing group:</bold> A clever design of a nitrile based catalyst directing group, serves as tool in the palladium‐catalyzed <italic>meta</italic>‐olefination of phenol derivatives. This group can be removed tracelessly, thus providing a convenient route to <italic>meta</italic>‐substitution of phenols, a transformation that cannot be conducted by classic aromatic substitution chemistry.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t7hh7zd" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>