Catalytic Bio‐Supramolecular Photochirogenesis: Batch‐Operated Enantiodifferentiating Photocyclodimerization of 2‐Anthracenecarboxylate with Human Serum Albumin. Issue 11 (5th June 2013)

• Record Type: Journal Article
• Authors: Nishijima, Masaki; Kato, Hanako; Yang, Cheng; Fukuhara, Gaku; Mori, Tadashi; Araki, Yasuyuki; Wada, Takehiko; Inoue, Yoshihisa
• Is Part Of: ChemCatChem. Volume 5:Issue 11(2013:Nov.)
• Page Start: 3237
• Page End: 3240
• Publication Date: 2013-06-05
• Subjects: Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201300160
• Languages: English
• ISSNs: 1867-3880

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Chiral induction:</bold> Catalytic bio‐supramolecular photochirogenesis is achieved for the enantiodifferentiating [4+4] photocyclodimerization of 2‐anthracenecarboxylate by repeatedly using human serum albumin (HSA) as a chiral mediator; the original high enantiomeric excess values (up to 80–90 %) are preserved.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t7d80tv" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>