Template‐Free Preparation of Volvox‐like CdxZn1−xS Nanospheres with Cubic Phase for Efficient Photocatalytic Hydrogen Production. Issue 3 (8th January 2014)

• Record Type: Journal Article
• Authors: Zhou, Hangyue; Liu, Qingyun; Liu, Weimin; Ge, Jiechao; Lan, Minhuan; Wang, Chao; Geng, Jianxin; Wang, Pengfei
• Is Part Of: Chemistry, an Asian journal. Volume 9:Issue 3(2014:Mar.)
• Page Start: 811
• Page End: 818
• Publication Date: 2014-01-08
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.201301428
• Languages: English
• ISSNs: 1861-4728

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Volvox‐like Cd_{<italic>x</italic>}Zn_{1−<italic>x</italic>}S solid solutions with a cubic zinc blend structure were synthesized through a template‐free ethylene glycol process. Cd(Ac)₂<bold>⋅</bold>2 H₂O, Zn(Ac)₂<bold>⋅</bold>2 H₂O, and thiourea are used as the starting materials and dissolved in ethylene glycol. These reaction precursors and solvent not only contributed to control over the formation of the volvox‐like spherical geometry, but also exerted vigorous domination for existence of cubic‐phase Cd_{<italic>x</italic>}Zn_{1−<italic>x</italic>}S nanostructures. As‐prepared volvox‐like Cd_{<italic>x</italic>}Zn_{1−<italic>x</italic>}S nanospheres have a diameter of around 100 nm with extensional shells. These samples show excellent photocatalytic H₂ evolution activity from water splitting under visible‐light irradiation without any cocatalyst or scaffolding, owing to their tunable band gap, cubic zinc blend structure, and unique hierarchical porous structure with a high surface area (as high as 95.2 m² g⁻¹).</p> </abstract>