1, 2‐Bis(ferrocenyl)‐Substituted Distibene and Dibismuthene: SbSb and BiBi Units as π Spacers between Two Ferrocenyl Units. Issue 4 (1st February 2013)

• Record Type: Journal Article
• Authors: Sakagami, Michiyasu; Sasamori, Takahiro; Sakai, Heisuke; Furukawa, Yukio; Tokitoh, Norihiro
• Is Part Of: Chemistry, an Asian journal. Volume 8:Issue 4(2013:Apr.)
• Page Start: 690
• Page End: 693
• Publication Date: 2013-02-01
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.201201227
• Languages: English
• ISSNs: 1861-4728

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Pi in the sky</bold>: 1, 2‐bis(ferrocenyl)distibene and 1, 2‐bis(ferrocenyl)dibismuthene derivatives, where two bulky ferrocenyl units are bridged by a SbSb and BiBi π spacer, have been synthesized as a new family of novel d–π conjugated systems. Their molecular structures, spectroscopic behavior, and electrochemical properties reveal the SbSb and BiBi units to be effective π‐electron spacers.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t763nm8" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>