Inside Cover: [ReF6]2−: A Robust Module for the Design of Molecule‐Based Magnetic Materials (Angew. Chem. Int. Ed. 5/2014). Issue 5 (21st January 2014)

• Record Type: Journal Article
• Authors: Pedersen, Kasper S.; Sigrist, Marc; Sørensen, Mikkel A.; Barra, Anne‐Laure; Weyhermüller, Thomas; Piligkos, Stergios; Thuesen, Christian Aa.; Vinum, Morten G.; Mutka, Hannu; Weihe, Høgni; Clérac, Rodolphe; Bendix, Jesper
• Is Part Of: Angewandte Chemie international edition. Volume 53:Issue 5(2014)
• Page Start: 1170
• Page End: 1170
• Publication Date: 2014-01-21
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201310970
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>A robust building block for magnetic systems is found as a result of a new high‐yield synthesis of the [ReF₆]^2– ion. K. S. Pedersen, R. Clérac, J. Bendix, and co‐workers report in their Communication on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 1351 ff.</ext-link> that on incorporating the [ReF₆]^2– in a Ni^II–Re^IV 1D coordination polymer, the fluoride mediates significant magnetic couplings. The ferromagnetic NiFRe interaction found (+11 cm^–1) dwarfs the values obtained in related cyanide‐bridged systems.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4sm9pfmw" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>