A Concerted Transfer Hydrogenolysis: 1, 3, 2‐Diazaphospholene‐Catalyzed Hydrogenation of NN Bond with Ammonia–Borane1. Issue 13 (24th February 2014)
- Record Type:
- Journal Article
- Title:
- A Concerted Transfer Hydrogenolysis: 1, 3, 2‐Diazaphospholene‐Catalyzed Hydrogenation of NN Bond with Ammonia–Borane1. Issue 13 (24th February 2014)
- Main Title:
- A Concerted Transfer Hydrogenolysis: 1, 3, 2‐Diazaphospholene‐Catalyzed Hydrogenation of NN Bond with Ammonia–Borane1
- Authors:
- Chong, Che Chang
Hirao, Hajime
Kinjo, Rei - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>1, 3, 2‐diazaphospholenes catalyze metal‐free transfer hydrogenation of a NN double bond using ammonia–borane under mild reaction conditions, thus allowing access to various hydrazine derivatives. Kinetic and computational studies revealed that the rate‐determining step involves simultaneous breakage of the BH and NH bonds of ammonia–borane. The reaction is therefore viewed as a concerted type of hydrogenolysis.</p> </abstract>
- Is Part Of:
- Angewandte Chemie international edition. Volume 53:Issue 13(2014)
- Journal:
- Angewandte Chemie international edition
- Issue:
- Volume 53:Issue 13(2014)
- Issue Display:
- Volume 53, Issue 13 (2014)
- Year:
- 2014
- Volume:
- 53
- Issue:
- 13
- Issue Sort Value:
- 2014-0053-0013-0000
- Page Start:
- 3342
- Page End:
- 3346
- Publication Date:
- 2014-02-24
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3773 ↗
http://www.interscience.wiley.com/jpages/1433-7851 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/anie.201400099 ↗
- Languages:
- English
- ISSNs:
- 1433-7851
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3072.xml