Oxidative Cyclization Reactions: Controlling the Course of a Radical Cation‐Derived Reaction with the Use of a Second Nucleophile1. Issue 49 (19th November 2013)

• Record Type: Journal Article
• Authors: Redden, Alison; Perkins, Robert J.; Moeller, Kevin D.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 49(2013)
• Page Start: 12865
• Page End: 12868
• Publication Date: 2013-11-19
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201308739
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Construction of new ring systems</bold>: Oxidative cyclizations (see picture; RVC=reticulated vitreous carbon) have been conducted that use two separate intramolecular nucleophiles to trap an enol ether‐derived radical cation intermediate. The reactions provide a means for rapidly trapping the radical cation intermediate in a manner that avoids competitive decomposition reactions.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t7b0hhw" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>