A Palladium‐Nanoparticle and Silicon‐Nanowire‐Array Hybrid: A Platform for Catalytic Heterogeneous Reactions1. Issue 1 (15th November 2013)

• Record Type: Journal Article
• Authors: Yamada, Yoichi M. A.; Yuyama, Yoshinari; Sato, Takuma; Fujikawa, Shigenori; Uozumi, Yasuhiro
• Is Part Of: Angewandte Chemie international edition. Volume 53:Issue 1(2014)
• Page Start: 127
• Page End: 131
• Publication Date: 2013-11-15
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201308541
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>We report the development of a silicon nanowire array‐stabilized palladium nanoparticle catalyst, SiNA‐Pd. Its use in the palladium‐catalyzed Mizoroki‐Heck reaction, the hydrogenation of an alkene, the hydrogenolysis of nitrobenzene, the hydrosilylation of an α, β‐unsaturated ketone, and the C‐H bond functionalization reactions of thiophenes and indoles achieved a quantitative production with high reusability. The catalytic activity reached several hundred‐mol ppb of palladium, reaching a TON of 2 000 000.</p> </abstract>