NHC‐Mediated Synthesis of an Asymmetric, Cationic Phosphoranide, a Phosphanide, and Coinage‐Metal Phosphanido Complexes1. Issue 52 (20th November 2013)

• Record Type: Journal Article
• Authors: Schwedtmann, Kai; Holthausen, Michael H.; Feldmann, Kai‐Oliver; Weigand, Jan J.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 52(2013)
• Page Start: 14204
• Page End: 14208
• Publication Date: 2013-11-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201308309
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A cationic phosphoranide</bold> featuring a normal and an abnormal imidazoliumyl substituent was prepared through the reaction of a P‐centered cation with an N‐heterocyclic carbene (NHC). The remarkable reactivity of this compound allows the formation of two‐ or three‐coordinate P‐centered cations, illustrating the ability of imidazoliumyl substituents to stabilize high‐ and low‐coordinated P atoms.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t3hz2sp" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>