Gold‐Catalyzed Synthesis of Tetrazoles from Alkynes by CC Bond Cleavage1. Issue 50 (13th November 2013)
- Record Type:
- Journal Article
- Title:
- Gold‐Catalyzed Synthesis of Tetrazoles from Alkynes by CC Bond Cleavage1. Issue 50 (13th November 2013)
- Main Title:
- Gold‐Catalyzed Synthesis of Tetrazoles from Alkynes by CC Bond Cleavage1
- Authors:
- Gaydou, Morgane
Echavarren, Antonio M. - Abstract:
- <abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Golden duality</bold>: Tetrazoles are formed by the reaction of alkynes with TMSN<sub>3</sub> (TMS=trimethylsilyl) in the presence of <italic>i</italic>PrOH and the gold(I) catalyst [JohnPhosAu(MeCN)]SbF<sub>6</sub>. In this transformation gold plays a dual role, first activating the alkyne and then generating a Brønsted acid in situ.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t3kjg4h" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>
- Is Part Of:
- Angewandte Chemie international edition. Volume 52:Issue 50(2013)
- Journal:
- Angewandte Chemie international edition
- Issue:
- Volume 52:Issue 50(2013)
- Issue Display:
- Volume 52, Issue 50 (2013)
- Year:
- 2013
- Volume:
- 52
- Issue:
- 50
- Issue Sort Value:
- 2013-0052-0050-0000
- Page Start:
- 13468
- Page End:
- 13471
- Publication Date:
- 2013-11-13
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3773 ↗
http://www.interscience.wiley.com/jpages/1433-7851 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/anie.201308076 ↗
- Languages:
- English
- ISSNs:
- 1433-7851
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 4089.xml