Field‐Induced Hysteresis and Quantum Tunneling of the Magnetization in a Mononuclear Manganese(III) Complex1. Issue 52 (19th November 2013)

• Record Type: Journal Article
• Authors: Vallejo, Julia; Pascual‐Álvarez, Alejandro; Cano, Joan; Castro, Isabel; Julve, Miguel; Lloret, Francesc; Krzystek, J.; De Munno, Giovanni; Armentano, Donatella; Wernsdorfer, Wolfgang; Ruiz‐García, Rafael; Pardo, Emilio
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 52(2013)
• Page Start: 14075
• Page End: 14079
• Publication Date: 2013-11-19
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201308047
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>There is plenty of room at the bottom</bold>: A gap in the literature of molecular nanomagnets has been filled with the preparation of the first mononuclear manganese(III) complex exhibiting a slow relaxation of the magnetization, that is, a species with a single slow‐relaxing, highly anisotropic Mn^III ion, as confirmed by very low‐temperature micro‐SQUID magnetization and high‐field EPR spectroscopic measurements (N blue, O red, Mn purple, Cl green).<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t3hxx6r" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>