A Uranium‐Based UO2+–Mn2+ Single‐Chain Magnet Assembled trough Cation–Cation Interactions1. Issue 3 (6th December 2013)

• Record Type: Journal Article
• Authors: Mougel, Victor; Chatelain, Lucile; Hermle, Johannes; Caciuffo, Roberto; Colineau, Eric; Tuna, Floriana; Magnani, Nicola; de Geyer, Arnaud; Pécaut, Jacques; Mazzanti, Marinella
• Is Part Of: Angewandte Chemie international edition. Volume 53:Issue 3(2014)
• Page Start: 819
• Page End: 823
• Publication Date: 2013-12-06
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201307366
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Single‐chain magnets (SCMs) are materials composed of magnetically isolated one‐dimensional (1D) units exhibiting slow relaxation of magnetization. The occurrence of SCM behavior requires the fulfillment of stringent conditions for exchange and anisotropy interactions. Herein, we report the synthesis, the structure, and the magnetic characterization of the first actinide‐containing SCM. The 5f–3d heterometallic 1D chains [{[UO₂(salen)(py)][M(py)₄](NO₃)}]_{<italic>n</italic>,} (M=Cd (<bold>1</bold>) and M=Mn (<bold>2</bold>); py=pyridine) are assembled trough cation–cation interaction from the reaction of the uranyl(V) complex [UO₂(salen)py][Cp*₂Co] (Cp*=pentamethylcyclopentadienyl) with Cd(NO₃)₂ or Mn(NO₃)₂ in pyridine. The infinite UMn chain displays a high relaxation barrier of 134±0.8 K (93±0.5 cm⁻¹), probably as a result of strong intra‐chain magnetic interactions combined with the high Ising anisotropy of the uranyl(V) dioxo group. It also exhibits an open magnetic hysteresis loop at <italic>T</italic>&lt;6 K, with an impressive coercive field of 3.4 T at 2 K.</p> </abstract>