Water Reduction with Visible Light: Synergy between Optical Transitions and Electron Transfer in Au‐TiO2 Catalysts Visualized by In situ EPR Spectroscopy1. Issue 43 (12th September 2013)

• Record Type: Journal Article
• Authors: Priebe, Jacqueline B.; Karnahl, Michael; Junge, Henrik; Beller, Matthias; Hollmann, Dirk; Brückner, Angelika
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 43(2013)
• Page Start: 11420
• Page End: 11424
• Publication Date: 2013-09-12
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201306504
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Golden electrons</bold>: Visible light excites conduction electron transfer from gold particles to support vacancies where they are taken up by protons to produce hydrogen. This transfer process was visualized by in situ EPR spectroscopy.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t3csbr2" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>