Liquid Coordination Complexes Formed by the Heterolytic Cleavage of Metal Halides1. Issue 48 (11th October 2013)

• Record Type: Journal Article
• Authors: Coleman, Fergal; Srinivasan, Geetha; Swadźba‐Kwaśny, Małgorzata
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 48(2013)
• Page Start: 12582
• Page End: 12586
• Publication Date: 2013-10-11
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201306267
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Confused complexes</bold>: Reaction of a range of donor molecules with AlCl₃ or GaCl₃, gives mobile liquids with very high metal contents. They contain statistically distributed mixtures of anionic, cationic, and neutral complexes in equilibrium. These liquid coordination complexes (LCCs), have high conductivity, tunable Lewis acidity, and low vapor pressure.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t7bqj97" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>