Bioinspired Iron‐Based Catalyst for Atom Transfer Radical Polymerization1. Issue 46 (23rd September 2013)

• Record Type: Journal Article
• Authors: Simakova, Antonina; Mackenzie, Matthew; Averick, Saadyah E.; Park, Sangwoo; Matyjaszewski, Krzysztof
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 46(2013)
• Page Start: 12148
• Page End: 12151
• Publication Date: 2013-09-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201306337
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Naturally occurring hemin</bold>, an iron‐containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t77rcvm" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>