DNA vs. Mirror‐Image DNA: A Universal Approach to Tune the Absolute Configuration in DNA‐Based Asymmetric Catalysis1. Issue 44 (12th September 2013)

• Record Type: Journal Article
• Authors: Wang, Jocelyn; Benedetti, Erica; Bethge, Lucas; Vonhoff, Stefan; Klussmann, Sven; Vasseur, Jean‐Jacques; Cossy, Janine; Smietana, Michael; Arseniyadis, Stellios
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 44(2013)
• Page Start: 11546
• Page End: 11549
• Publication Date: 2013-09-12
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201306232
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Mirror mirror on the wall</bold>: By taking advantage of the unique structural features of <sc>L</sc>‐DNA, the first examples of left‐helical enantioselective induction in the field of DNA‐based asymmetric catalysis were realized. Most importantly, this approach is the only one that allows a reliable and predictable access to both enantiomers for any given reaction.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t6z7k4w" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>