A Strongly Emitting Liquid‐Crystalline Derivative of Y3N@C80: Bright and Long‐Lived Near‐IR Luminescence from a Charge Transfer State1. Issue 47 (7th October 2013)

• Record Type: Journal Article
• Authors: Toth, Kalman; Molloy, Jennifer K.; Matta, Micaela; Heinrich, Benoît; Guillon, Daniel; Bergamini, Giacomo; Zerbetto, Francesco; Donnio, Bertrand; Ceroni, Paola; Felder‐Flesch, Delphine
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 47(2013)
• Page Start: 12303
• Page End: 12307
• Publication Date: 2013-10-07
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201305536
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Great balls of fire</bold>: C₆₀ and Y₃N@C₈₀ were connected to the same oligo(phenyleneethynylene) unit to investigate their structural and photophysical properties. NMR investigations revealed a fulleroid structure for the Y₃N@C₈₀ derivative, and both dyads gave rise to columnar phases with core‐shell cylinders. The black and gray spheres represent the fullerene core units of the Y₃N@C₈₀ derivative, which is an ideal candidate to be involved in energy and electron transfer processes.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t78sqsm" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>