Ambident Reactivities of Formaldehyde N, N‐Dialkylhydrazones1. Issue 45 (19th September 2013)

• Record Type: Journal Article
• Authors: Maji, Biplab; Troshin, Konstantin; Mayr, Herbert
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 45(2013)
• Page Start: 11900
• Page End: 11904
• Publication Date: 2013-09-19
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201305092
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>What can attack at carbon?</bold> With a nucleophilicity <italic>N</italic>≈7 for attack at the azomethine carbon, formaldehyde hydrazones can undergo noncatalyzed reactions at room temperature with electrophiles that have a reactivity parameter <italic>E</italic> that is greater than −12.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t72q4ph" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>