An Anionic Microporous Polymer Network Prepared by the Polymerization of Weakly Coordinating Anions1. Issue 46 (22nd October 2013)

• Record Type: Journal Article
• Authors: Fischer, Sabrina; Schmidt, Johannes; Strauch, Peter; Thomas, Arne
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 46(2013)
• Page Start: 12174
• Page End: 12178
• Publication Date: 2013-10-22
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201303045
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Organic zeolite</bold>: A microporous, covalent organic network with high surface area was synthesized by polymerization of [B(C₆F₄Br)₄]⁻. The countercations, located within the pore channels, are highly accessible and can be easily exchanged, comparable to the extra‐framework cations in zeolites. In this way a [Mn^II(bpy)]²⁺ complex can be synthesized and immobilized in the network.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4t77rgj6" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>