Palladium‐Catalyzed ortho‐Selective CH Deuteration of Arenes: Evidence for Superior Reactivity of Weakly Coordinated Palladacycles1. (29th November 2013)
- Record Type:
- Journal Article
- Title:
- Palladium‐Catalyzed ortho‐Selective CH Deuteration of Arenes: Evidence for Superior Reactivity of Weakly Coordinated Palladacycles1. (29th November 2013)
- Main Title:
- Palladium‐Catalyzed ortho‐Selective CH Deuteration of Arenes: Evidence for Superior Reactivity of Weakly Coordinated Palladacycles1
- Authors:
- Ma, Sandy
Villa, Giorgio
Thuy‐Boun, Peter S.
Homs, Anna
Yu, Jin‐Quan - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>We disclose a protocol for the palladium‐catalyzed <italic>ortho</italic>‐selective CH deuteration of arenes. Phenylacetic acids and benzoic acids are suitable substrates for this reaction. This reaction offers a catalytic route to <italic>ortho</italic>‐deuterated phenylacetic acids and benzoic acids and demonstrates the sharp difference in reactivity of palladacycle intermediates held together by weak and strong coordination.</p> </abstract>
- Is Part Of:
- Angewandte Chemie. Volume 126:Number 3(2014)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 126:Number 3(2014)
- Issue Display:
- Volume 126, Issue 3 (2014)
- Year:
- 2014
- Volume:
- 126
- Issue:
- 3
- Issue Sort Value:
- 2014-0126-0003-0000
- Page Start:
- 753
- Page End:
- 756
- Publication Date:
- 2013-11-29
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201305388 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 3207.xml