Transition Metal‐Mediated Direct CH Arylation of Heteroarenes Involving Aryl Radicals. Issue 4 (31st January 2014)

• Record Type: Journal Article
• Authors: Bonin, Hélène; Sauthier, Mathieu; Felpin, François‐Xavier
• Is Part Of: Advanced synthesis & catalysis. Volume 356:Issue 4(2014)
• Page Start: 645
• Page End: 671
• Publication Date: 2014-01-31
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201300865
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>This review gives an overview of the generation of aryl radicals, mediated by transition metals, and their use for the CH arylation of heteroarenes. The different sources of aromatic derivatives able to generate aryl radicals <italic>via</italic> a metal‐assisted reduction or oxidation are discussed, with a critical view of the developed systems. The radical arylations of nitrogen‐, oxygen‐ or sulfur‐containing heterocycles are then described and mechanistic considerations are discussed as well.</p> <p> <boxed-text content-type="graphic" position="anchor" orientation="portrait"> <graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4sx6063q" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> </boxed-text> </p> </abstract>