Palladium‐Catalysed Dehydrogenative sp3 CH Bonds Functionalisation into Alkenes: A Direct Access to N‐Alkenylbenzenesulfonamides. Issue 1 (13th January 2014)

• Record Type: Journal Article
• Authors: Bheeter, Charles B.; Jin, Rongwei; Bera, Jitendra K.; Dixneuf, Pierre H.; Doucet, Henri
• Is Part Of: Advanced synthesis & catalysis. Volume 356:Issue 1(2014)
• Page Start: 119
• Page End: 124
• Publication Date: 2014-01-13
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201300795
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The palladium‐catalysed dehydrogenation of <italic>sp</italic>³ carbon‐hydrogen bonds of <italic>N</italic>‐alkylbenzenesulfonamides allows a simple access to <italic>N</italic>‐alkenylbenzenesulfonamides. The reaction proceeds with easily accessible catalysts, with pivalate as a base, and allows a variety of substituents both on nitrogen and on the arene moiety.</p> <p> <boxed-text content-type="graphic" position="anchor" orientation="portrait"> <graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4sm495x5" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> </boxed-text> </p> </abstract>