A Generic Synthetic Approach to Large‐Scale Pristine‐Graphene/Metal‐Nanoparticles Hybrids. (20th June 2013)

• Record Type: Journal Article
• Authors: Wang, Xiujuan; Meng, Guowen; Zhu, Chuhong; Huang, Zhulin; Qian, Yiwu; Sun, Kexi; Zhu, Xiaoguang
• Is Part Of: Advanced functional materials. Volume 23:Number 46(2013)
• Page Start: 5771
• Page End: 5777
• Publication Date: 2013-06-20
• Subjects: Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201301409
• Languages: English
• ISSNs: 1616-301X

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The homogeneous attachment of metal‐nanoparticles (metal‐NPs) on pristine‐graphene surface to construct pristine‐graphene/metal‐NPs hybrids is highly expected for application in many fields such as transparent electrodes and conductive composites. However, it remains a great challenge since the pristine‐graphene is highly hydrophobic. Here, an environmentally friendly generic synthetic approach to large‐scale pristine‐graphene/metal‐NPs hybrids is presented, by a combinatorial process of exfoliating expanded graphite in N‐methyl pyrrolidone via sonication and centrifugation to achieve the pristine‐graphene, and attaching pre‐synthesized metal‐NPs on the pristine‐graphene in ethanol via van der Waals interactions between the metal‐NPs and the pristine‐graphene. Nanoparticles of different metals (such as Ag, Au, and Pd) with various morphologies (such as sphere, cube, plate, multi‐angle, and spherical‐particle assembling) can be homogeneously attached on the defect‐free pristine‐graphene with controlled packing densities. Both the pristine‐graphene and the metal‐NPs preserve their original intrinsic structures. The as‐synthesized pristine‐graphene/Ag‐NPs hybrids show very high surface‐enhanced Raman scattering activity due to the combined effects of large surface area of the pristine‐graphene to adsorb more target molecules and the electromagnetic enhancement of the Ag‐NPs. This large‐scale synthesis of the pristine‐graphene/metal‐NPs hybrids with tunable shape and packing density of metal‐NPs opens up opportunities for fundamental research and potential applications ranging from devices to transparent electrodes and conductive composites.</p> </abstract>