Click Construction of Spiro‐ and Bridged‐Quatrefoil Polymer Topologies with Kyklo‐Telechelics Having an Azide Group. Issue 4 (6th September 2013)

• Record Type: Journal Article
• Authors: Ko, Yee Song; Yamamoto, Takuya; Tezuka, Yasuyuki; Lutz, J.‐F.; Sumerlin, B.; Matyjaszewski, K.
• Is Part Of: Macromolecular rapid communications. Volume 35:Issue 4(2014:Feb.)
• Page Start: 412
• Page End: 416
• Publication Date: 2013-09-06
• Subjects: Macromolecules -- Periodicals; Polymers -- Periodicals; Chemistry -- Periodicals; 547.705
• DOI: 10.1002/marc.201300555
• Languages: English
• ISSNs: 1022-1336

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>Unprecedented tetracyclic polymer topologies with spiro‐ and a bridged‐type quatrefoil forms are effectively constructed through an alkyne‐azide, click‐linking reaction by employing a kyklo‐telechelic poly(tetrahydrofuran), poly(THF), precursor having an azide group, obtained through an electrostatic self‐assembly and covalent fixation (ESA‐CF) process, and complementary tetrafunctional alkyne reagents of either a pentaerythritol derivative or a four‐armed star telechelic polymer precursor. <boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg4svm6wxr" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>