Nitrogen‐Containing Polycyclic Quinones as Cathode Materials for Lithium‐ion Batteries with Increased Voltage. Issue 2 (10th February 2014)

• Record Type: Journal Article
• Authors: Shimizu, Akihiro; Tsujii, Yutaka; Kuramoto, Hiroki; Nokami, Toshiki; Inatomi, Yuu; Hojo, Nobuhiko; Yoshida, Jun‐ichi
• Is Part Of: Energy technology. Volume 2:Issue 2(2014:Feb.)
• Page Start: 155
• Page End: 158
• Publication Date: 2014-02-10
• Subjects: Energy development -- Periodicals; Power resources -- Periodicals; 333.79
• DOI: 10.1002/ente.201300148
• Languages: English
• ISSNs: 2194-4288

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Although organic cathode materials have received significant research interest as cathode materials of lithium‐ion batteries because of sustainability and flexibility, they suffer from lower voltages compared to inorganic materials. To increase the voltage of batteries using organic cathode materials without decreasing the capacity, we studied the effect of the replacement of the CH moieties β to the carbonyl group of quinones with nitrogen atoms. The coordination of N to Li in the reduced forms and the greater electronegativity of N compared to C make reduction energetically more favorable. The lithium batteries based on the nitrogen analogues of quinones as cathode materials exhibited voltages higher than 3.0 V (the first stage).</p> </abstract>