A Base‐Stabilized Sila‐β‐Lactone and a Donor/Acceptor‐Stabilized Silanoic Acid1. Issue 34 (16th July 2013)

• Record Type: Journal Article
• Authors: Rodriguez, Ricardo; Gau, David; Troadec, Thibault; Saffon‐Merceron, Nathalie; Branchadell, Vicenç; Baceiredo, Antoine; Kato, Tsuyoshi
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 34(2013)
• Page Start: 8980
• Page End: 8983
• Publication Date: 2013-07-16
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201304482
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A stable</bold> base‐stabilized sila‐β‐lactone was successfully synthesized and fully characterized. Interestingly, this sila‐β‐lactone shows a very unique reactivity toward ethanol, leading to the formation of an isolable donor/acceptor‐stabilized silanoic acid.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg36jz8fkf" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>