Slow Magnetic Relaxation in a CoII–YIII Single‐Ion Magnet with Positive Axial Zero‐Field Splitting1. Issue 35 (14th July 2013)

• Record Type: Journal Article
• Authors: Colacio, Enrique; Ruiz, José; Ruiz, Eliseo; Cremades, Eduard; Krzystek, J.; Carretta, Stefano; Cano, Joan; Guidi, Tatiana; Wernsdorfer, Wolfgang; Brechin, Euan K.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 35(2013)
• Page Start: 9130
• Page End: 9134
• Publication Date: 2013-07-14
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201304386
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A magnetic Co‐production</bold>: The complex [Co(μ‐L)(μ‐OAc)Y(NO₃)₂] (see structure O red, N blue, C gray), in which the Co^II ion exhibits a <italic>D</italic> value of approximately +45 cm⁻¹, as determined by magnetic and inelastic neutron scattering experiments, exhibits slow magnetic relaxation and single‐ion magnet behavior.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg36jzxnkq" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>