Direct Observation of Molecular Orbital Mixing in a Solvated Organometallic Complex1. Issue 37 (23rd July 2013)

• Record Type: Journal Article
• Authors: Suljoti, Edlira; Garcia‐Diez, Raul; Bokarev, Sergey I.; Lange, Kathrin M.; Schoch , Roland; Dierker, Brian; Dantz, Marcus; Yamamoto, Kenji; Engel, Nicholas; Atak, Kaan; Kühn, Oliver; Bauer, Matthias; Rubensson, Jan‐Erik; Aziz, Emad F.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 37(2013)
• Page Start: 9841
• Page End: 9844
• Publication Date: 2013-07-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201303310
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Fundamental processes</bold>: Charge donation/backdonation in the [Fe(CO)₅] molecule in solution was measured by resonant inelastic X‐ray scattering. This method can be used to selectively probe the electronic structure at each atom in the iron–carbonyl bond.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg36jzx35t" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>