Combinations of Ethers and B(C6F5)3 Function as Hydrogenation Catalysts1. Issue 29 (14th June 2013)

• Record Type: Journal Article
• Authors: Hounjet, Lindsay J.; Bannwarth, Christoph; Garon, Christian N.; Caputo, Christopher B.; Grimme, Stefan; Stephan, Douglas W.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 29(2013)
• Page Start: 7492
• Page End: 7495
• Publication Date: 2013-06-14
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201303166
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>It works ether way</bold>: Labile adducts of dialkyl ethers with the electrophilic borane B(C₆F₅)₃ are shown to scramble HD to H₂ and D₂ and catalyze the hydrogenation of 1, 1‐diphenylethylene.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg270vv8k4" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>