Total Synthesis of Indotertine A and Drimentines A, F, and G1. Issue 35 (15th July 2013)

• Record Type: Journal Article
• Authors: Sun, Yu; Li, Ruofan; Zhang, Wenhao; Li, Ang
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 35(2013)
• Page Start: 9201
• Page End: 9204
• Publication Date: 2013-07-15
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201303334
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Oh my darling, Drimentine</bold>: The first total synthesis of the pyrroloindoline alkaloids drimentines A, F, and G, and their congener, indotertine A, is reported. An intermolecular radical conjugate addition was key in the synthesis of the drimentine alkaloids, and a biologically inspired iminium–olefin cyclization converted drimentine F into indotertine A.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg36jzx62q" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>