Atroposelective Self‐Assembly of a Molecular Capsule from Amphiphilic Anthracene Trimers1. Issue 31 (19th June 2013)

• Record Type: Journal Article
• Authors: Suzuki, Akira; Kondo, Kei; Akita, Munetaka; Yoshizawa, Michito
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 31(2013)
• Page Start: 8120
• Page End: 8123
• Publication Date: 2013-06-19
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201302789
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Atroposelective formation</bold>: Selective formation of a molecular capsule was demonstrated from an amphiphilic <italic>cis</italic>‐atropisomer bearing three anthracene rings and four sulfonate groups through hydrophobic and aromatic–aromatic interactions. The dimeric capsule binds small guest molecules; the resultant host–guest complexes exhibit ground‐state charge‐transfer interactions accompanied by changes in host emission.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg276x4g26" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>