Controlled Growth of Dichlorogermanium Oligomers from Lewis Basic Hosts1. Issue 25 (27th May 2013)

• Record Type: Journal Article
• Authors: Al‐Rafia, S. M. Ibrahim; Momeni, Mohammad R.; McDonald, Robert; Ferguson, Michael J.; Brown, Alex; Rivard, Eric
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 25(2013)
• Page Start: 6390
• Page End: 6395
• Publication Date: 2013-05-27
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201302767
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>To branch or not to branch</bold>: A mild stepwise route to various linear and branched (GeCl₂)_{<italic>x</italic>} oligogermylenes supported by Lewis bases is reported, including the carbene‐bound Ge₄ complex NHC⋅GeCl₂Ge(GeCl₃)₂ (see picture). Dipp=2, 6‐<italic>i</italic>Pr₂C₆H₃, NHC=N‐heterocyclic carbene.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg21kr241j" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>