Synthesis of (+)‐Schisanwilsonene A by Tandem Gold‐Catalyzed Cyclization/1, 5‐Migration/Cyclopropanation1. Issue 25 (10th May 2013)

• Record Type: Journal Article
• Authors: Gaydou, Morgane; Miller, Ricarda E.; Delpont, Nicolas; Ceccon, Julien; Echavarren, Antonio M.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 25(2013)
• Page Start: 6396
• Page End: 6399
• Publication Date: 2013-05-10
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201302411
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Going (anti)viral</bold>: The first total synthesis of the antiviral (+)‐schisanwilsonene A has been completed using a fully stereoselective tandem cyclization/1, 5‐migration/intermolecular cyclopropanation. The key reaction sequence is catalyzed by gold.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg21kr288g" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>