Assembly and Stepwise Oxidation of Interpenetrated Coordination Cages Based on Phenothiazine1. Issue 38 (23rd July 2013)

• Record Type: Journal Article
• Authors: Frank, Marina; Hey, Jakob; Balcioglu, Ilker; Chen, Yu‐Sheng; Stalke, Dietmar; Suenobu, Tomoyoshi; Fukuzumi, Shunichi; Frauendorf, Holm; Clever, Guido H.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 38(2013)
• Page Start: 10102
• Page End: 10106
• Publication Date: 2013-07-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201302536
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A breath of fresh air</bold> is sufficient for the eightfold S‐monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square‐planar‐coordinated Pd^II cations. Besides these two cages, which were both characterized by X‐ray crystallography, an eightfold S‐dioxygenated double‐cage was obtained under harsher oxidation conditions.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg37r9mgjk" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>