Back Cover: Resonance Raman Spectroscopy as a Tool to Monitor the Active Site of Hydrogenases (Angew. Chem. Int. Ed. 19/2013). Issue 19 (22nd April 2013)

• Record Type: Journal Article
• Authors: Siebert, Elisabeth; Horch, Marius; Rippers, Yvonne; Fritsch, Johannes; Frielingsdorf, Stefan; Lenz, Oliver; Velazquez Escobar, Francisco; Siebert, Friedrich; Paasche, Lars; Kuhlmann, Uwe; Lendzian, Friedhelm; Mroginski, Maria‐Andrea; Zebger, Ingo; Hildebrandt, Peter
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 19(2013)
• Page Start: 5186
• Page End: 5186
• Publication Date: 2013-04-22
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201302121
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>The biological conversion of hydrogen</bold> is catalyzed by [NiFe] hydrogenases utilizing a tailored bimetallic center. In their Communication on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 5162 ff.</ext-link> P. Hildebrandt, I. Zebger, M. Horch, and co‐workers use resonance Raman spectroscopy for the first time to characterize this active site by directly probing Fe–CO/CN vibrational modes. Applying an integrated spectroscopic and computational approach, this method provides new insights into structural and photochemical aspects of the [NiFe] site.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1zsxjgpk" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>