A Magnesium‐Mediated Cascade Assembly for the Atom‐Economical Synthesis of Bis(imidazolidine‐2, 4‐dione)s1. Issue 20 (15th April 2013)

• Record Type: Journal Article
• Authors: Hill, Michael S.; Liptrot, David J.; Mahon, Mary F.
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 20(2013)
• Page Start: 5364
• Page End: 5367
• Publication Date: 2013-04-15
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201301489
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Bicycle race</bold>: Structurally complex bis(imidazolidine‐2, 4‐dione) molecules may be synthesized with complete atom‐efficiency from simple building blocks by a kinetically controlled magnesium‐mediated cascade of intermolecular isocyanate insertion and intramolecular alkyne hydroamination reaction steps.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1zsxhn2r" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>