Formation of Azaborines by Photoelimination of B, N‐Heterocyclic Compounds1. Issue 17 (5th April 2013)

• Record Type: Journal Article
• Authors: Lu, Jia‐Sheng; Ko, Soo‐Byung; Walters, Nicholas R.; Kang, Youngjin; Sauriol, Francoise; Wang, Suning
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 17(2013)
• Page Start: 4544
• Page End: 4548
• Publication Date: 2013-04-05
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201300873
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Highly fluorescent</bold> π‐conjugated polycyclic azaborines can be prepared from B, N‐heterocyclic compounds with a BR₂‐CH₂ unit through the elimination of an R‐H molecule (see scheme). These clean photoelimination reactions occur both in solution and in polymers doped with the precursors.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1xps7vg6" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>