An Yttrium Hydride–Silane Complex as a Structural Model for a σ‐Bond Metathesis Transition State1. Issue 15 (7th March 2013)

• Record Type: Journal Article
• Authors: Zhou, Jiliang; Chu, Jiaxiang; Zhang, Yanyan; Yang, Guang; Leng, Xuebing; Chen, Yaofeng
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 15(2013)
• Page Start: 4243
• Page End: 4246
• Publication Date: 2013-03-07
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201300638
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>A structural model</bold> for the transition state of the σ‐bond metathesis between SiH and ME bonds (M: d⁰ transition metal) was obtained through the formation of an yttrium hydride–silane complex (see picture). The silane moiety can be either retained or released during the reactions of the complex with other substrates.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1x47ftc4" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>