A High‐Valent Heterobimetallic [CuIII(μ‐O)2NiIII]2+ Core with Nucleophilic Oxo Groups1. Issue 21 (15th April 2013)

• Record Type: Journal Article
• Authors: Kundu, Subrata; Pfaff, Florian Felix; Miceli, Enrico; Zaharieva, Ivelina; Herwig, Christian; Yao, Shenglai; Farquhar, Erik R.; Kuhlmann, Uwe; Bill, Eckhard; Hildebrandt, Peter; Dau, Holger; Driess, Matthias; Limberg, Christian; Ray, Kallol
• Is Part Of: Angewandte Chemie international edition. Volume 52:Issue 21(2013)
• Page Start: 5622
• Page End: 5626
• Publication Date: 2013-04-15
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201300861
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>Cores and effect</bold>: Unlike homobimetallic analogues, the heterobimetallic CuNi bis(μ‐oxo) diamond core has nucleophilic oxo groups. A similar heterobimetallic core may, therefore, act as a viable intermediate during the deformylation of fatty aldehydes by cyanobacterial aldehyde decarbonylase.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgg1zsx7nh2" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>